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The '''''α''-factor''' is a [[dimensionless quantity]] used to predict the solid–liquid [[Interface (chemistry)|interface]] type of a material during [[Freezing|solidification]]. It was introduced by physicist Kenneth A. Jackson in 1958. In his model, crystal growth with larger values of ''α'' is smooth, whereas crystals growing at smaller ''α'' (below the threshold value of 2) have rough surfaces.<ref>{{cite journal|last=Bennema |first=P. |year=1993 |title=Morphology of crystals determined by alpha factors, roughening temperature, F faces and connected nets |journal=Journal of Physics D: Applied Physics |volume=26 |number=8B |pages=B1–B6 |doi=10.1088/0022-3727/26/8b/001}}</ref><ref>{{cite web|url=https://www.nae.edu/312073.aspx |title=Kenneth A. Jackson (1930&ndash;2022) |website=[[National Academy of Engineering]] |access-date=2024-04-01 |year=2022 |first1=Don |last1=Uhlmann |first2=Vincent |last2=Fratello}}</ref>
The '''''α''-factor''' is a [[dimensionless quantity]] used to predict the solid–liquid [[Interface (chemistry)|interface]] type of a material during [[Freezing|solidification]]. It was introduced by physicist Kenneth A. Jackson in 1958. In his model, crystal growth with larger values of ''α'' is smooth, whereas crystals growing at smaller ''α'' (below the threshold value of 2) have rough surfaces.<ref>{{cite journal|last=Bennema |first=P. |year=1993 |title=Morphology of crystals determined by alpha factors, roughening temperature, F faces and connected nets |journal=Journal of Physics D: Applied Physics |volume=26 |number=8B |pages=B1–B6 |doi=10.1088/0022-3727/26/8b/001}}</ref><ref>{{cite web|url=https://www.nae.edu/312073.aspx |title=Kenneth A. Jackson (1930&ndash;2022) |website=[[National Academy of Engineering]] |access-date=2024-04-01 |year=2022 |first1=Don |last1=Uhlmann |first2=Vincent |last2=Fratello}}</ref>


==Method==
== Method ==
According to John E. Gruzleski in his book ''Microstructure Development During Metalcasting'' (1996):
According to John E. Gruzleski in his book ''Microstructure Development During Metalcasting'' (1996):
: <math>\alpha = \frac{L}{kT_\mathrm{E}}\cdot\frac{\eta}{v} </math>

where <math>L</math> is the [[latent heat of fusion]]; <math>k</math> is the [[Boltzmann constant]]; <math>T_\mathrm{E}</math> is the [[Freezing point|freezing temperature]] at equilibrium; <math>\eta</math> is the number of nearest neighbours an [[atom]] has in the interface [[Plane (geometry)|plane]]; and <math>v</math> is the number of nearest neighbours in the bulk solid.
:<math>\alpha = \frac{L}{kT_\mathrm{E}}\cdot\frac{\eta}{v} </math>

where <math>L</math> is the [[latent heat of fusion]]; <math>k</math> is [[Boltzmann’s constant]]; <math>T_\mathrm{E}</math> is the [[Freezing point|freezing temperature]] at equilibrium; <math>\eta</math> is the number of nearest neighbours an [[atom]] has in the interface [[Plane (geometry)|plane]]; and <math>v</math> is the number of nearest neighbours in the bulk solid.


As <math>\frac{L}{T_\mathrm{E}} = \Delta S_f</math>, where <math>\Delta S_f</math> is the [[molar concentration|molar]] [[entropy of fusion]] of the material,
As <math>\frac{L}{T_\mathrm{E}} = \Delta S_f</math>, where <math>\Delta S_f</math> is the [[molar concentration|molar]] [[entropy of fusion]] of the material,
: <math>\alpha = \frac{\Delta S_f}{k} \cdot \frac{\eta}{v}</math> <ref name="gruzleski">{{cite book |last1=Gruzleski |first1=John E. |title=Microstructure Development During Metalcasting |date=1996}}</ref>

:<math>\alpha = \frac{\Delta S_f}{k} \cdot \frac{\eta}{v}</math> <ref name="gruzleski">{{cite book |last1=Gruzleski |first1=John E. |title=Microstructure Development During Metalcasting |date=1996}}</ref>


According to Martin Glicksman in his book ''Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts'' (2011):
According to Martin Glicksman in his book ''Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts'' (2011):
: <math>\alpha = \frac{\Delta S_f}{R_\mathrm{g}} \cdot\frac{\eta_1}{Z}</math>

:<math>\alpha = \frac{\Delta S_f}{R_\mathrm{g}} \cdot\frac{\eta_1}{Z}</math>

where <math>R_\mathrm{g}</math> is the [[universal gas constant]]. <math>\frac{\eta_1}{Z}</math> is similar to previous, always <math>\frac{1}{4} < \frac{\eta_1}{Z}</math> < 1.<ref name="glicksman">{{cite book |last1=Glicksman |first1=Martin |title=Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts |date=2011}}</ref>
where <math>R_\mathrm{g}</math> is the [[universal gas constant]]. <math>\frac{\eta_1}{Z}</math> is similar to previous, always <math>\frac{1}{4} < \frac{\eta_1}{Z}</math> < 1.<ref name="glicksman">{{cite book |last1=Glicksman |first1=Martin |title=Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts |date=2011}}</ref>


==References==
== References ==
{{reflist}}
{{reflist}}


[[Category:Materials science]]
[[Category:Materials science]]



{{CMP-stub}}
{{CMP-stub}}

Latest revision as of 11:39, 29 June 2024

The α-factor is a dimensionless quantity used to predict the solid–liquid interface type of a material during solidification. It was introduced by physicist Kenneth A. Jackson in 1958. In his model, crystal growth with larger values of α is smooth, whereas crystals growing at smaller α (below the threshold value of 2) have rough surfaces.[1][2]

Method

[edit]

According to John E. Gruzleski in his book Microstructure Development During Metalcasting (1996):

where is the latent heat of fusion; is the Boltzmann constant; is the freezing temperature at equilibrium; is the number of nearest neighbours an atom has in the interface plane; and is the number of nearest neighbours in the bulk solid.

As , where is the molar entropy of fusion of the material,

[3]

According to Martin Glicksman in his book Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts (2011):

where is the universal gas constant. is similar to previous, always < 1.[4]

References

[edit]
  1. ^ Bennema, P. (1993). "Morphology of crystals determined by alpha factors, roughening temperature, F faces and connected nets". Journal of Physics D: Applied Physics. 26 (8B): B1–B6. doi:10.1088/0022-3727/26/8b/001.
  2. ^ Uhlmann, Don; Fratello, Vincent (2022). "Kenneth A. Jackson (1930–2022)". National Academy of Engineering. Retrieved 2024-04-01.
  3. ^ Gruzleski, John E. (1996). Microstructure Development During Metalcasting.
  4. ^ Glicksman, Martin (2011). Principles of Solidification: An Introduction to Modern Casting and Crystal Growth Concepts.